
<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/">
  <dc:identifier>https://phaidrabg.bg.ac.rs/o:28850</dc:identifier>
  <dc:identifier>doi:10.6060/mhc200389s</dc:identifier>
  <dc:identifier>ISSN: 1998-9539</dc:identifier>
  <dc:creator>Heinemann, Frank W.</dc:creator>
  <dc:creator>Bugarčić, Živadin D.</dc:creator>
  <dc:creator id="https://orcid.org/0000-0003-3010-6503">Soldatović, Tanja V.</dc:creator>
  <dc:source>Macroheterocycles 13(3)</dc:source>
  <dc:language>eng</dc:language>
  <dc:date>2020</dc:date>
  <dc:format>application/pdf</dc:format>
  <dc:format>1113852 bytes</dc:format>
  <dc:title xml:lang="eng">Crystal Structures of trans-Diiodidobis(2-hydroxyethylamine) platinum(II) and trans-Dichloridobis(2,2’-dihydroxydiethylamine) platinum(II)</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:subject xml:lang="eng">Keywords: Platinum(II) complexes, 2-hydroxyethylamine, 2,2’-dihydroxydiethylamine</dc:subject>
  <dc:description xml:lang="eng">Abstract: The crystal structures of trans-diiodidobis(2-hydroxyethylamine)platinum(II), trans-[PtI2(mea)2], (1) and transdichloridobis(
2,2’-dihydroxydiethylamine)platinum(II), trans-[PtCl2(dea)2], (2) were determined by single crystal
X-ray diffraction experiments. Crystallization of (1) occurs in the monoclinic space group P21/c with a = 9.457(1) Å,
b = 14.719(2) Å, c = 8.246(1) Å, Z = 4 for dcalc = 3.235 mg/m3 while crystallization of (2) occurs in the tetragonal space
group P42/mbc, a = 9.8624(6) Å, c = 14.2998(9) Å, Z = 4 for dcalc = 2.274 mg/m3. The square-planar coordination
geometry of both complexes is formed by two N atoms of the 2-hydroxyethylamine (1) or 2,2’-dihydroxydiethylamine
(2) ligands in trans positions and two I- (1) or Cl- (2) anions. Both structures are stabilized by intra- and intermolecular
hydrogen bonds.
</dc:description>
  <dc:rights>All rights reserved</dc:rights>
</oai_dc:dc>